Photoelectrocatalytic Performances of Nanostructured/Decorated TiO 2

The behaviour of TiO2 based electrodes was investigated during the photoelectrocatalytic water splitting process. TiO2 nanotubes and compact oxide structures were obtained by electrochemical oxidation of Ti foils. A subsequent hydrothermal process carried out at both the nanotubular and compact oxide structures allowed decorating the structure by TiO2 nanoparticles. The synthesized TiO2 samples worked as photoanodes both in a bulk three electrode cell and in a thin gap cell. The results from measurements of the photocurrent and from electrochemical impedance spectroscopy were used to highlight a combined effect of the wavelength of the incident light and the kind of cell configuration, on the global performance of the systems. The results indicate that the decoration process does not result only in a simple increase of the specific surface, but it also determines a different concentration of the bulk and superficial sites in the electrode. The different response of the sites at different wavelengths, along with the accessibility of the electrolyte to the porous structure are evocated to justify the experimental behaviour observed

Controlling the Er content of porous silicon using the doping current intensity

The results of an investigation on the Er doping of porous silicon are presented. Electrochemical impedance spectroscopy, optical reflectivity, and spatially resolved energy dispersive spectroscopy (EDS) coupled to scanning electron microscopy measurements were used to investigate on the transient during the first stages of constant current Er doping. Depending on the applied current intensity, the voltage transient displays two very different behaviors, signature of two different chemical processes. The measurements show that, for equal transferred charge and identical porous silicon (PSi) layers, the applied current intensity also influences the final Er content. An interpretative model is proposed in order to describe the two distinct chemical processes. The results can be useful for a better control over the doping process

analysis of photocurrent and capacitance of tio2 nanotube polyaniline hybrid composites synthesized through electroreduction of an aryldiazonium salt

TiO2 nanotube–polyaniline hybrid composites were synthesized using an aminophenyl under-layer electrochemically grafted on TiO2 obtaining improvements in photocurrent and capacitance

Investigation on the Adsorption and Photooxidation of Glycerol at TiO2 Nanotubular Arrays

A study is presented on the adsorption of glycerol at TiO2as well as on its oxidative process during the contemporary water Photoelectro-splitting for hydrogen production. A deepening in the understanding on the working mechanism of the TiO2nanotubular photoanodes and on the interactions between glycerol and these structures has been gained through photocurrent tests, voltammetric scans, and EIS analysis. A range of wavelength of the incident radiation is investigated from 340 to 400 nm at which the effect of glycerol on the photocurrent is measured. Quantitative analysis of the EIS results is performed by the equivalent circuit approach

Increase in 20–50 Hz (gamma frequencies) power spectrum and synchronization after chronic vagal nerve stimulation

Objective: Though vagus nerve stimulation (VNS) is an important option in pharmacoresistant epilepsy, its mechanism of action remains unclear. The observation that VNS desynchronised the EEG activity in animals suggested that this mechanism could be involved in VNS antiepileptic effects in humans. Indeed VNS decreases spiking bursts, whereas its effects on the EEG background remain uncertain. The objective of the present study is to investigate how VNS affects local and inter regional syncronization in different frequencies in pharmacoresistent partial epilepsy. Methods: Digital recordings acquired in 11 epileptic subjects 1 year and 1 week before VNS surgery were compared with that obtained 1 month and 1 year after VNS activation. Power spectrum and synchronization were then analyzed and compared with an epileptic group of 10 patients treated with AEDs only and with 9 non-epileptic patients. Results: VNS decreases the synchronization of theta frequencies (P!0.01), whereas it increases gamma power spectrum and synchronization (!0.001 and 0.01, respectively). Conclusions: The reduction of theta frequencies and the increase in power spectrum and synchronization of gamma bands can be related to VNS anticonvulsant mechanism. In addition, gamma modulation could also play a seizure-independent role in improving attentional performances. Significance: These results suggest that some antiepileptic mechanisms affected by VNS can be modulated by or be the reflection of EEG changes.2026-2036Pubblicat

Assessing the impact of design factors on the performance of two miniature microbial fuel cells

Every day, wastewater treatment requires large amounts of electricity. Microbial Fuel Cells (MFCs) can convert wastewater treatment plants from net power consumers into energy neutral/positive systems by generating electricity from wastewaters. We investigate here the design factors that have major impacts on the performance of two miniature MFCs, and, consequently, of the resulting stack of MFCs. A versatile mathematical model is provided, which simulates the complex MFC system by integrating fluid dynamic principles with mass transport phenomena and (bio)electrochemical reactions. The model is used to support an in-depth study of the two MFCs, which differ for electrode spacing, anodic volume and fluid pattern within the anodic chamber, and to associate any difference in performance to design factors. Finally, system scale-up is demonstrated by generating stacks of the two MFCs. Thanks to the versatility of the model developed, this study becomes a guide for the effective development of future miniature MFCs

Accurate dust temperature and star formation rate in the most luminous z>6z>6 quasar in the HYPerluminous quasars at the Epoch of ReionizatION (HYPERION) sample

We present ALMA Band 9 continuum observation of the ultraluminous quasi-stellar object (QSO) SDSS J0100+2802, providing a $\sim 10\sigma$ detection at $\sim 670$ GHz. SDSS J0100+2802 is the brightest QSO with the most massive super massive black hole (SMBH) known at $z>6$, and we study its dust spectral energy distribution in order to determine the dust properties and the star formation rate (SFR) of its host-galaxy. We obtain the most accurate estimate so far of the temperature, mass and emissivity index of the dust, having $T_{\rm dust}=48.4\pm2.3$ K, $M_{\rm dust}=(2.29\pm0.83)\times 10^7$ M$_\odot$, $\beta=2.63\pm 0.23$. This allows us to measure the SFR with the smallest statistical error for this QSO, SFR$=265\pm 32\ \rm M_\odot yr^{-1}$. Our results enable us to evaluate the relative growth of the SMBH and host galaxy of J0100+2802, finding that the SMBH is dominating the process of BH-galaxy growth in this QSO at $z=6.327$, when the Universe was $865$ Myr old. Such unprecedented constraints on the host galaxy SFR and dust temperature can only be obtained through high frequency observations, and highlight the importance of ALMA Band 9 to obtain a robust overview of the build-up of the first quasars' host galaxies at $z>6$.Comment: 10 pages, 4 figures, 1 table. Accepted for publication in ApJ

Early Results from GLASS-JWST. XXI: Rapid assembly of a galaxy at z=6.23 revealed by its C/O abundance

The abundance of carbon relative to oxygen (C/O) is a promising probe of star formation history in the early universe, as the ratio changes with time due to production of these elements by different nucleosynthesis pathways. We present a measurement of $\log{\mathrm{(C/O)}} = -1.01\pm0.12$ (stat) $\pm0.15$ (sys) in a $z=6.23$ galaxy observed as part of the GLASS-JWST Early Release Science Program. Notably, we achieve good precision thanks to the detection of the rest-frame ultraviolet O III], C III], and C IV emission lines delivered by JWST/NIRSpec. The C/O abundance is $\sim$0.8 dex lower than the solar value and is consistent with the expected yield from core-collapse supernovae, indicating that longer-lived intermediate mass stars have not fully contributed to carbon enrichment. This in turn implies rapid buildup of a young stellar population with age $\lesssim100$ Myr in a galaxy seen $\sim$900 million years after the Big Bang. Our chemical abundance analysis is consistent with spectral energy distribution modeling of JWST/NIRCam photometric data, which indicates a current stellar mass $\log\,\mathrm{M}_* / \mathrm{M_{sun}} = 8.4^{+0.4}_{-0.2}$ and specific star formation rate sSFR $\simeq 20$ Gyr$^{-1}$. These results showcase the value of chemical abundances and C/O in particular to study the earliest stages of galaxy assembly.Comment: 16 pages, 4 figures, 2 tables. Accepted for publication in ApJ

Early results from GLASS-JWST. III: Galaxy candidates at z∼\sim9-15

We present the results of a first search for galaxy candidates at z$\sim$9--15 on deep seven-bands NIRCam imaging acquired as part of the GLASS-JWST Early Release Science Program on a flanking field of the Frontier Fields cluster A2744. Candidates are selected via two different renditions of the Lyman-break technique, isolating objects at z$\sim$9-11, and z$\sim$9-15, respectively, supplemented by photometric redshifts obtained with two independent codes. We find six color-selected candidates at z$>$9, plus one additional candidate with photometric redshift z$_{phot}\geq$9. In particular, we identify two bright candidates at $m_{F150W}\simeq 26$ that are unambiguously placed at $z\simeq 10.6$ and $z\simeq 12.3$, respectively. The total number of galaxies discovered at $z>9$ is in line with the predictions of a non-evolving LF. The two bright ones at $z>10$ are unexpected given the survey volume, although cosmic variance and small number statistics limits general conclusions. This first search demonstrates the unique power of JWST to discover galaxies at the high redshift frontier. The candidates are ideal targets for spectroscopic follow-up in cycle$-2$.Comment: Submitted to ApJL, 9 pages, 4 figure